@Entity
public class Student {
    @Id int studentId;
    ...
    @ManyToMany  // students and courses are also many-many
    @JoinTable(name="ENROLLMENTS",
        joinColumns=@JoinColumn(name="STUDENT"),
        inverseJoinColumns=@JoinColumn(name="SEMESTER"))
    @MapKeyJoinColumn(name="COURSE")
    Map<Course, Semester>  enrollment;
    ...
}

TABLE enrollments (
    student_id bigint NOT NULL,
    semester_id bigint NOT NULL,
    course_id bigint,
    CONSTRAINT enrollments_pkey PRIMARY KEY (student_id, semester_id)
)